Abstract
The combination of four iso-nicotinate appended tetrathiacalix[4]arene (TCA-1) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl2 and Hg(II)Cl2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl2 and a 2D grid-like network with, Hg(II)Cl2. The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.
Keywords
Chemistry
Cobalt
Mercury (programming language)
Derivative (finance)
Metal
Coordination polymer
Coordination complex
Stereochemistry
Crystallography
Single crystal
Crystal structure
Inorganic chemistry
Organic chemistry
Subject Areas
Metal-Organic Frameworks: Synthesis and Applications
·Inorganic Chemistry ·Physical Sciences
Supramolecular Chemistry and Complexes
·Organic Chemistry ·Physical Sciences
Magnetism in coordination complexes
·Electronic, Optical and Magnetic Materials ·Physical Sciences
OpenAlex SDG Match
SDGs auto-classified by OpenAlex (score ≥ 0.4 shown).
Clean water and sanitation 53%
Loading…