Journal Article

·2010 OPEN ACCESS

[2,3,7,8,13,14,17,18-Octakis(ethylsulfanyl)-5,10,15,20-porphyrazinato]zinc(II)

Mehmet Akkurt , Nacıye Yılmaz Coşkun YTU , Fatma Aytan Kılıçaslan YTU , Sabiha Manav Yalçın YTU , Orhan Büyükgüngör , Ahmet Gül

Acta Crystallographica Section E Structure Reports Online

Abstract

In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intra-molecular C-H⋯N and C-H⋯S inter-actions contribute to the stability of the mol-ecular conformation. Inter-molecular C-H⋯S contacts, weak C-H⋯π inter-actions and π-π stacking inter-actions [centroid-centriod distances = 3.832 (4) and 3.850 (5) Å] contribute to the stabilization of the crystal structure.

Keywords

Stacking Crystallography Chemistry Zinc Ion Atom (system on chip) Symmetry (geometry) Planar Crystal structure Square pyramidal molecular geometry Crystal (programming language) Mathematics Geometry

Subject Areas

Porphyrin and Phthalocyanine Chemistry ·Materials Chemistry ·Physical Sciences
Crystal structures of chemical compounds ·Inorganic Chemistry ·Physical Sciences
Metal complexes synthesis and properties ·Oncology ·Health Sciences