Journal Article

·2019

A Comparative Study of Optical Properties of Thin Films of MPS-encapsulated CdS Quantum Dots and SiO2/MPS-encapsulated CdS Quantum Dots Mixture

Kenan Koç YTU

Optics and Spectroscopy

Abstract

The aim of this study is to investigate the optical properties of thin films of MPS-encapsulated CdS quantum dots (QDs) and SiO2/MPS-encapsulated CdS QDs mixture. For this purpose, SiO2 sol and colloidal MPS-encapsulated CdS QDs were mixed and then deposited on a glass substrate by spin coating. Also, the spin coating method was used to deposit the colloid-produced MPS-encapsulated CdS QDs and in this way the QDs were self-assembled onto the glass substrate. The films were heat treated at 150°C under N2 atmosphere. The optical properties of the films were characterized by UV-Vis absorption spectrophotometer and NKD spectrophotometer measurements. The refractive index and thickness of the films were calculated by fitting the measured data in a Drude–Lorentz model. The refractive index values were found 1.90 and 1.51 for the thin films of the MPS-encapsulated CdS QDs and SiO2/QDs mixtures, respectively. According to this result, the refractive index value of the SiO2/CdS QDs mixture thin film is close to the glass substrate and such films may be a good candidate for planar luminous solar concentrators.

Keywords

Materials science Quantum dot Refractive index Thin film Spin coating Substrate (aquarium) Colloid Optoelectronics Chemical engineering Nanotechnology

Subject Areas

Quantum Dots Synthesis And Properties ·Materials Chemistry ·Physical Sciences
Chalcogenide Semiconductor Thin Films ·Electrical and Electronic Engineering ·Physical Sciences
TiO2 Photocatalysis and Solar Cells ·Renewable Energy, Sustainability and the Environment ·Physical Sciences

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