Preprint

·2024 OPEN ACCESS

Advanced Electrochemical Fabrication of Bimetallic Alloy Anchored Flexible Catalysts for Efficient Hydrogen Evolution Reaction

M. Giray Ersozoglu , Hürmüs Gürsu YTU , A. Sezai̇ Saraç YTU , Yücel Şahin YTU

Research Square

Abstract

Recently, nickel-cobalt/graphene-based hybrid electrocatalysts have gained significant attention for their use in hydrogen evolution reactions (HER). In this study, we report a facile electrochemical synthesis route for cobalt (Co) and nickel (Ni) doped/anchored graphene-like carbon fiber electrocatalysts, achieved in a single step using Yucel's method. The spectroscopic, morphological, and crystallographic structures of the Ni-Co alloys were analyzed in solutions containing various molar ratios of Ni:Co. The Ni-Co doped/anchored graphene-like carbon fiber electrocatalysts exhibited significantly enhanced electrocatalytic activity for HER compared to single metallic doped Ni and Co electrocatalysts. Notably, the Ni-Co@GrF2 electrocatalyst demonstrated the smallest Tafel slope 42 mV dec-1, which is comparable to the electrocatalytic activity of platinum..

Keywords

Bimetallic strip Fabrication Alloy Electrochemistry Catalysis Materials science Nanotechnology Chemical engineering Metallurgy Chemistry Electrode Engineering Organic chemistry Physical chemistry

Subject Areas

Electrocatalysts for Energy Conversion ·Renewable Energy, Sustainability and the Environment ·Physical Sciences
Hydrogen embrittlement and corrosion behaviors in metals ·Metals and Alloys ·Physical Sciences
Fuel Cells and Related Materials ·Electrical and Electronic Engineering ·Physical Sciences