Book Chapter

·2017

Application of Calcium Carbonate for the Removal of Copper from Aqueous Solutions.

Semra Kırboğa YTU , Mualla Öner YTU

Abstract

Abstract. In the present work we studied the effect of calcium carbonate on the adsorption behavior of Cu(II). Calcium carbonate (CaCO3) obtained in the absence and presence of biopolymer, carboxymethy inulin (CMI), was used as an adsorbent. The effect of sintering process and the particles obtained in the absence and presence of biopolymer on the adsorption capacity of calcium carbonate were investigated. The adsorption capacity increased with sintering of calcium carbonate. The results showed that the Cu(II) adsorption rate was fast and most of Cu(II) was adsorbed within 5 minute. The adsorption kinetics were tested based on modified Freundlich, pseudo-first-order, and pseudo-second-order equations. While pseudo-first-order equation was suitable for the adsorption kinetics obtained by using sintered calcium carbonate (CaCO3), the adsorption kinetic was best described by modified Freundlich equation for experiments carried out by using non-sintered calcium carbonate.

Keywords

Copper Calcium carbonate Aqueous solution Carbonate Calcium Chemistry Materials science Metallurgy Organic chemistry

Subject Areas

Adsorption and biosorption for pollutant removal ·Water Science and Technology ·Physical Sciences