Abstract
Abstract The intrinsic viscosity data of linear poly(4‐chlorostyrene) in n ‐propylbenzene and isopropylbenzene were used to estimate the equation of state exchange energy ( X 12 ) and entropy ( Q 12 ) parameters. The quantities estimated for X 12 were 6.7 and 8.1 J cm −3 and those of Q 12 were −0.069 and −0.063 J cm −3 deg −1 in n ‐propylbenzene and isopropylbenzene, respectively. The average values of the chain unperturbed dimension constant ( K o ) and the characteristic ratio ( C x ) were found to be 0.55 × 10 −3 dl mol 1/2 g −3/2 and 10.54, respectively, from the intrinsic viscosities measured at the corresponding θ‐temperatures.
Keywords
Intrinsic viscosity
Thermodynamics
Viscosity
Polymer
Solvent
Entropy (arrow of time)
Chemistry
Analytical Chemistry (journal)
Materials science
Physics
Chromatography
Organic chemistry
Subject Areas
Thermodynamic properties of mixtures
·Fluid Flow and Transfer Processes ·Physical Sciences
Ionic liquids properties and applications
·Catalysis ·Physical Sciences
Chemical and Physical Properties in Aqueous Solutions
·Filtration and Separation ·Physical Sciences
OpenAlex SDG Match
SDGs auto-classified by OpenAlex (score ≥ 0.4 shown).
Affordable and clean energy 85%
Loading…
Loading…