Journal Article

·2013

Evaluation of magnesium wastes for the synthesis of magnesium borate hydrates by microwave energy

Fatma Tuğçe Şenberber YTU , Azmi Seyhun Kıpçak YTU , Emek Möröydor Derun YTU , Sabriye Pişkin YTU

Journal of selçuk üniversity natural and applied science

Abstract

Metal wastes should be stored carefully due their human and environment health effects. Evaluation of metal wastes can be an alternative way instead of storage. In this study, it is aimed to reuse the magnesium wastes by the synthesis of magnesium borate minerals using microwave energy. Dry raw materials were slurred with 1 ml of water to faciliate reaction of the mixture. Mixture of waste of magnesium and boric acid, at mole ratio of 1:4, reacted at 360W. Effect of reaction time to product was studied.After synthesis stage, X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FT-IR) were applied to final products. According to XRD patterns,three types of magnesium hydrate borate minerals were synthesized. Synthesized minerals were Admontite (PDF No: 00-034-1438, MgO(B 2 O 3 ) 3 .7(H 2 O)), Inderite (PDF No: 00-036-0423) and Kurnacovite (PDF No: 01-072-1890, Mg 2 B 6 O 11 .15H 2 O). Characteristic vibration peak values are determined by FT-IRanalysis. It is seen that structure of synthesized magnesium borate mineral changes with the reaction time.

Keywords

Magnesium Boric acid Boron Hydrate Fourier transform infrared spectroscopy Raw material Nuclear chemistry Metal Chemistry Mineral Inorganic chemistry Materials science Chemical engineering Organic chemistry

Subject Areas

MXene and MAX Phase Materials ·Materials Chemistry ·Physical Sciences
Nuclear materials and radiation effects ·Materials Chemistry ·Physical Sciences
Advanced ceramic materials synthesis ·Ceramics and Composites ·Physical Sciences