Journal Article

·2008 OPEN ACCESS

Freezing in Halide Salts

Ünsal Akdere YTU , M. Yitur lmaz YTU , H. Birtan Kavanoz YTU , Çetin Taşseven YTU

Acta Physica Polonica A

Abstract

The static criterion that the amplitude of the principal peak of the liquid structure factor has a constant value along the freezing line and the onset of freezing are studied from the structure factors and the static dielectric functions of halide salts interacting via the effective pair potentials through the hypernetted-chain approximation. It is observed that the criterion above is restricted to the effective charge difference. The critical value of plasma parameter at freezing is affected by the mobility and number concentration of anions and cations. The distribution of the value of the static dielectric function closest to the wave number axis in the negative region is also determined by the charge difference and the ordering of ions and related to the onset of freezing.

Keywords

Halide Materials science Chemistry Inorganic chemistry

Subject Areas

Advanced Physical and Chemical Molecular Interactions ·Physical and Theoretical Chemistry ·Physical Sciences
Freezing and Crystallization Processes ·Mechanics of Materials ·Physical Sciences