Journal Article

·2023

How does the isophthalic unsaturated polyester affect the dielectric properties, the glass transition, and the ductility of bitumen?

Kemal Ulutaş , Şahin Yakut , Deniz Bozoglu , B.D. Sitilbay YTU , Mustafa Karaşahin , S. Yardım YTU , Deniz Değer

Road Materials and Pavement Design

Abstract

AbstractBitumen with 50/70 penetration was prepared and modified by doping with the unsaturated polyester resin based on isophthalic acid at 5% by weight (w/w%).The structural, mechanical, and thermal properties of bitumen and bitumen modified with unsaturated polyester resin %5 (UPR) were determined. The dielectric properties of bitumen and modified bitumen were investigated in the frequency and temperature ranges of 0.1-106 Hz and (-)40°C- 40°C, respectively. Polarization mechanisms, glass-transition temperature, and ductility of all samples were determined and compared to each other. The glass transition temperature of the modified bitumen shifts toward low temperatures in comparison to the bitumen. So, it can be suggested that the use of modified bitumen is very attractive in regions where the temperature differences are high. Also, the dielectric analysis method is an innovative alternative to determining modified bitumen's low-temperature performance. It was found that the modification with UPR provide strength and flexibility to asphalt.KEYWORDS: AC conductivitybitumenbitumen modified with unsaturated polyester resindielectric relaxationglass transition temperaturethicknessSubject classification codes: Bitumendielectric spectroscopyglass transition temperaturemodificationpolyester Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis study was supported by the Scientific Research Projects Coordination Unit of Istanbul University under project numbers 37896 and 30048.Bilimsel Araştirma Projeleri Birimi, Istanbul Üniversitesi.

Keywords

Glass transition Materials science Asphalt Composite material Isophthalic acid Ductility (Earth science) Polyester Dielectric Polymer

Subject Areas

Asphalt Pavement Performance Evaluation ·Civil and Structural Engineering ·Physical Sciences
Polymer Nanocomposites and Properties ·Polymers and Plastics ·Physical Sciences
High voltage insulation and dielectric phenomena ·Materials Chemistry ·Physical Sciences

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