Journal Article

·2012

Hydrothermally Mixed Hydroxyapatite–Multiwall Carbon Nanotubes Composite Coatings on Biomedical Alloys by Electrophoretic Deposition

C. B. Ustundag YTU , Oğuzhan Avcıata YTU , Figen Kaya YTU , Cengiz Kaya YTU

The Journal of Physical Chemistry B

Abstract

Hydroxyapatite (HA) coatings have been used to improve biological and mechanical fixation of metallic prosthesis. Because of extraordinary features of carbon nanotubes (CNTs), they have a lot of facilities, such as extremely strong nanoreinforcement materials for composites. HA powders were synthesized and mixed with multiwalled carbon nanotubes (MWCNTs) by a hydrothermal process. Calcium acetate (Ca (CH(3)COO)(2)) and phosphoric acid (H(3)PO(4)) were used as starting materials for synthesizing nano-HA powders. HA-MWCNTs were treated together hydrothermally at 200 °C for 2 h to synthesize nano-HA powders mixed homogeneously with MWCNTs. Cathodic deposits were obtained on Ti-based alloys using suspensions containing nano-HA and MWCNTs dispersed in n-butanol solvent. It was shown that MWCNTs interacted with HA powders during hydrothermal processing, and therefore, they can easily be dispersed within aqueous-based suspensions. It was also shown that hydrothermal surface modification of MWCNTs with functional groups was achievable, which was a significant step toward eliminating nonwetting surface behavior of MWCNTs, resulting in obtaining homogeneous dispersion of them in liquids.

Keywords

Electrophoretic deposition Materials science Carbon nanotube Hydrothermal circulation Chemical engineering Composite number Dispersion (optics) Aqueous solution Composite material Coating Organic chemistry Chemistry

Subject Areas

Electrophoretic Deposition in Materials Science ·Electrical and Electronic Engineering ·Physical Sciences
Bone Tissue Engineering Materials ·Biomedical Engineering ·Physical Sciences
Layered Double Hydroxides Synthesis and Applications ·Materials Chemistry ·Physical Sciences

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