Journal Article

·2018 OPEN ACCESS

İSTANBUL’DA KIŞ HAVA ŞARTLARINDA ATMOSFERİK ORGANOKLORLU PESTİSİT SEVİYELERİ VE GAZ/PARTİKÜL DAĞILIMLARI

S. Levent Kuzu YTU

Uludağ University Journal of The Faculty of Engineering

Abstract

In this study, gas and particle phase ambient organochlorine pesticide (OCP) levels were investigated atan urban site in Istanbul. Samples were collected by a high-volume sampler for fourteen days in winter. Individual OCP concentrations were between13 and 593 pg.m -3 for particle phase and 14 and 1,748 pg.m -3 for gaseous phase. The sums of the average concentration of each OCP in gaseous and particle phases were 3,219 and 2,746 pg.m -3 , respectively. δ-HCH had the highest individual concentration. The abundance of DDTs followed the order 4.4'-DDT > 4.4'-DDD > 4.4'-DDE.The Σ(gas+particle)OCP concentrations ranged between 1,845 and 10,196 pg.m -3 . On the days when high concentrations were observed, the trajectories of air masses were investigated by the HYSPLIT model. logKp versus logP L 0 model was applied in order to determine the fate of gas/particle partitioning. The average slope of the regression line was -0.35, whereas the intercept was -2.89.

Keywords

Chemistry Gas phase Particle (ecology) Analytical Chemistry (journal) Environmental chemistry Chromatography Animal science Organic chemistry Geology

Subject Areas

Pesticide and Herbicide Environmental Studies ·Pollution ·Physical Sciences
Pesticide Residue Analysis and Safety ·Food Science ·Life Sciences
Toxic Organic Pollutants Impact ·Health, Toxicology and Mutagenesis ·Physical Sciences

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