Abstract
New ligand based on p-tertbutyltetrathiacalix[4]arene blocked in 1,3-alternate conformation, was achieved via a multistep synthesis with the introduction of thiomethylpropoxy groups on the lower rim which leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalix[4]arene (p-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF6 salt, leads to the formation of neutral, new 2-D coordination network, which was structurally investigated in the solid state by X-ray diffraction methods on a single crystal.
Keywords
Chemistry
Ligand (biochemistry)
Crystallography
Ring (chemistry)
Group (periodic table)
Solid-state
Salt (chemistry)
Stereochemistry
Tetrahedron
Receptor
Organic chemistry
Subject Areas
Metal-Organic Frameworks: Synthesis and Applications
·Inorganic Chemistry ·Physical Sciences
Magnetism in coordination complexes
·Electronic, Optical and Magnetic Materials ·Physical Sciences
Metal complexes synthesis and properties
·Oncology ·Health Sciences
Citations by Year
2024: 1
OpenAlex SDG Match
SDGs auto-classified by OpenAlex (score ≥ 0.4 shown).
Clean water and sanitation 41%
Loading…
Loading…