Journal Article

·1998

Oxidation Stability of Some Phosphorus - Free Fully Formulated Crankcase Oils

B.A. Khorramian , Hakan Kaleli̇ YTU , Joseph M. Perez

SAE technical papers on CD-ROM/SAE technical paper series

Abstract

<div class="htmlview paragraph">Legislation world-wide has made it necessary to find ways to control the level of engine emissions and reduce the damage to our environment. Increasing restrictions have made the elimination of zinc dithiophosphates from crankcase oils and increasing the effectiveness of catalytic converters viable options. Lead and phosphorus containing compounds in the exhaust are known catalyst poisons that shorten the life of current automotive catalysts. Unleaded fuel has successfully resulted in a reduction of harmful emissions due to the fuel. Current government and industry research is actively pursuing replacement of phosphorus additives with phosphorus free additives. Several phosphorus-free oils were developed and are evaluated in bench tests in this study. Test comparisons with phosphorus- containing oils demonstrated satisfactory oxidation stability and wear performance of the phosphorus free oils.</div>

Keywords

Crankcase Phosphorus Chemistry Environmental science Automotive engineering Engineering Organic chemistry Internal combustion engine

Subject Areas

Thermal and Kinetic Analysis ·Materials Chemistry ·Physical Sciences
Pesticide Exposure and Toxicity ·Plant Science ·Life Sciences
Polymer Science and PVC ·Polymers and Plastics ·Physical Sciences