Journal Article

·2010

Preparation and Metal Sorption Properties of GMA-MMA-DVB Microspheres Functionalized with 2-Aminothiazole

Hale Berber YTU , Güzin Alpdoğan YTU , Bürge Aşçı YTU , Hüseyin Yıldırım YTU , Sıdıka Sungur YTU

Analytical Letters

Abstract

Abstract Crosslinked glycidylmethacrylate-methylmethacrylate-divinylbenzen (GMA-MMA-DVB) microspheres were prepared by suspension polymerization. The GMA-MMA-DVB microspheres with an average size of 150–300 μm and surface area of 1.51 m2g−1 were functionalized with 2-aminothiazole (ATAL). The affinity of the functionalized microspheres for copper, iron, aluminum, lead, cobalt, and nickel ions was examined. The effects of pH, resin amount, shaking time, type, and volume of the elution solution on the sorption and desorption properties of functionalized microspheres for these metal ions were investigated using the batch method. Sorption capacities (0.97–1.12 mmolg−1), quantitation limits (2.6–3.0 ppb) and recoveries (90–99%) were calculated. Keywords: 2-AminothiazoleChelating microspheresGlycidylmethacrylate copolymerMetal sorptionSuspension polymerization Notes *A: percent adsorption, R: percent recovery.

Keywords

Chemistry Sorption Suspension polymerization Adsorption Metal ions in aqueous solution Nuclear chemistry Polymerization Cobalt Microsphere Desorption Elution Metal Nickel Chromatography Chemical engineering Inorganic chemistry Organic chemistry Polymer

Subject Areas

Analytical chemistry methods development ·Analytical Chemistry ·Physical Sciences
Electrochemical sensors and biosensors ·Electrical and Electronic Engineering ·Physical Sciences
Analytical Chemistry and Sensors ·Bioengineering ·Physical Sciences

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