Journal Article

·2006

Rigidity of heat‐treated oriented isotactic polypropylene

Katherina Tsobkallo , А. А. Тихомиров , Altan Bozdoğan YTU , A. Tshmel

Journal of Applied Polymer Science

Abstract

Abstract Uniaxially oriented commercial films of isotactic polypropylene were strained with ends keeping fixed and subjected to the heat treatment at temperatures from 50 to 200°C. The rigidity of annealed samples was characterized by the value of tangent modulus, E t , determined graphically at the initial portions of stress–strain curves. The structural changes in the samples were studied with the help of the IR and low‐frequency Raman spectroscopies. The smallest E t values were obtained for the low‐strained films, while the tangent moduli measured for highly strained samples exceeded the value for the original (untreated) film. The most prominent positive effect was achieved after annealing the samples at 90°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 6074–6080, 2006

Keywords

Tacticity Materials science Composite material Annealing (glass) Tangent modulus Raman spectroscopy Dissipation factor Polypropylene Tangent Moduli Modulus Rigidity (electromagnetism) Polymer Polymerization Mathematics Optics Dielectric Physics

Subject Areas

Polymer Nanocomposites and Properties ·Polymers and Plastics ·Physical Sciences
Polymer crystallization and properties ·Polymers and Plastics ·Physical Sciences
Polymer Science and Applications ·Mechanical Engineering ·Physical Sciences

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