Abstract
Abstract Folding of azide functionalized polymer chains was obtained via the copper‐catalyzed azide alkyne cycloaddition (CuAAC) methodology using a light‐responsive crosslinker as the ‘click’ component. Subsequently, crosslinked junction points were combined with a photoinduced radical combination strategy to achieve more compact nanoparticles. The resultant folding particles possess smaller particle sizes and higher glass transition temperature values compared to their linear analogues. Fourier transform IR spectroscopy, SEC, DSC, dynamic light scattering, 1 H NMR and TEM techniques were used for characterization. © 2020 Society of Chemical Industry
Keywords
Azide
Click chemistry
Polymer
Dynamic light scattering
Materials science
Cycloaddition
Fourier transform infrared spectroscopy
Nanoparticle
Glass transition
Folding (DSP implementation)
Polymer chemistry
Light scattering
Chemical engineering
Photochemistry
Chemistry
Scattering
Nanotechnology
Catalysis
Organic chemistry
Composite material
Subject Areas
Advanced Polymer Synthesis and Characterization
·Organic Chemistry ·Physical Sciences
Machine Learning in Materials Science
·Materials Chemistry ·Physical Sciences
Block Copolymer Self-Assembly
·Materials Chemistry ·Physical Sciences
Citations by Year
2021: 2
2025: 3
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