Journal Article

·2018

Syntheses of 1,3-bis(2-arylimino)isondoline type ligands and some metal complexes containing EDOT moiety

Özge Göktuğ YTU , Sıbel Eken Korkut YTU , Büşra Nur Gökçe YTU , Tuğçe Yazıcı Tekbaşoğlu YTU , M. Kasım Şener YTU

Main Group Chemistry

Abstract

EDOT (3,4-ethylenedioxythiophene) substituted 1,3-bis(2-arylimino)isoindoline derivatives EDOT-BAI1, EDOT-BAI2, EDOT-BAI3, and EDOT-BAI4 have been synthesized according to the Linstead or Siegl’s method. Preparation of palladium(II) and platinum(II) complexes of EDOT-BAI1 and EDOT-BAI2 have been also accomplished in this study. The new compounds have been characterized by FT-IR, NMR, UV-Vis spectroscopies and via mass spectrometric analysis. The present EDOT derivatives provide new starting materials that may be useful in the synthesis of new, functional electropolymers.

Keywords

Chemistry Isoindoline Moiety Palladium Metal Polymer chemistry Combinatorial chemistry Organic chemistry Catalysis

Subject Areas

Conducting polymers and applications ·Polymers and Plastics ·Physical Sciences
Analytical Chemistry and Sensors ·Bioengineering ·Physical Sciences
Organic Electronics and Photovoltaics ·Electrical and Electronic Engineering ·Physical Sciences