Abstract
4,5-Diazafluorene ligands, (L1) and (L2), have been synthesized from the reaction of 4,5-diazafluorenone-9-hydrazone with 4-(4-fluorophenoxy) benzaldehyde and 4,5-diazafluoren-9-one with 4-(4-fluorophenoxy) benzylamine hydrochloride in dry EtOH. Ru(II) complexes of the ligands Ru(II)-L1 and Ru(II)-L2 were prepared by treating the ligands with Ru(bpy)2CI2 in dry EtOH. The metal-to-ligand ratio of the Ru(II) complexes was found to be 1:1. The ligands and complexes were characterized by elemental analysis and spectra FTIR, UV-vis, 1H NMR, MS, and fluorescence studies.
Keywords
Chemistry
Fluorene
Hydrazone
Benzylamine
Ruthenium
Benzaldehyde
Ligand (biochemistry)
Medicinal chemistry
Proton NMR
Elemental analysis
Metal
Fourier transform infrared spectroscopy
Nuclear chemistry
Polymer chemistry
Stereochemistry
Inorganic chemistry
Catalysis
Organic chemistry
Polymer
Subject Areas
Inorganic and Organometallic Chemistry
·Organic Chemistry ·Physical Sciences
Metal complexes synthesis and properties
·Oncology ·Health Sciences
TiO2 Photocatalysis and Solar Cells
·Renewable Energy, Sustainability and the Environment ·Physical Sciences
Citations by Year
2017: 1
2023: 1
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