Abstract
The synthesis, photophysical and spectroscopic properties of soluble 2-(ethyl)-1,3-dioxanethio-substituted metal-free and metalloporphyrazines containing Mg(II), Zn(II), Co(II) and Ni(II) are reported. The aggregation behaviour of these compounds was investigated in different solvents and concentrations. The effects of the substituent and the nature of the metal ion on the photophysical parameters of the Mg(II), Zn(II), Co(II) and Ni(II) porphyrazines are also reported.
Keywords
Substituent
Chemistry
Fluorescence
Metal
Metal ions in aqueous solution
Nuclear chemistry
Ion
Inorganic chemistry
Medicinal chemistry
Polymer chemistry
Photochemistry
Organic chemistry
Subject Areas
Porphyrin and Phthalocyanine Chemistry
·Materials Chemistry ·Physical Sciences
Luminescence and Fluorescent Materials
·Materials Chemistry ·Physical Sciences
Photochemistry and Electron Transfer Studies
·Physical and Theoretical Chemistry ·Physical Sciences
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