Journal Article

·2019

Synthesis of new polyhedral oligomeric silsesquioxane derivatives as some possible antimicrobial agents

Elif Basak Ersoy YTU , Ömer Tahir Günkara YTU , Nüket Öcal YTU

Phosphorus, sulfur, and silicon and the related elements

Abstract

1,3-Dipolar cycloaddition reactions were studied to synthesize Polyhedral oligomeric silsesquioxane (POSS)-based norbornyl imide derivatives containing izoxazoline groups in good yields. And also 1,3-dipolar cycloaddition reactions of azomethine ylides with POSS-based norbornene dipolarophiles for a synthesis of the novel POSS-based norbornane-fused spiro-1,3-indandionolylpyrrolidines are reported. All newly synthesized POSS compounds were structurally characterized by FTIR, 1H, 13C NMR, HRMS and GC/MS analyses.

Keywords

Silsesquioxane Norbornane Cycloaddition Norbornene 1,3-Dipolar cycloaddition Imide Chemistry Carbon-13 NMR Polymer chemistry Organic chemistry Catalysis Polymerization Polymer

Subject Areas

Silicone and Siloxane Chemistry ·Materials Chemistry ·Physical Sciences
Synthesis and properties of polymers ·Polymers and Plastics ·Physical Sciences
Antimicrobial agents and applications ·Organic Chemistry ·Physical Sciences

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