Journal Article

·2015

Synthesis, Preparation, and Characterization of Liquid Crystal/Organo-Montmorillonite Nanocomposites

Serap Mutlu-Yanic YTU , Dilek Güzeller YTU , Hale Ocak YTU , Fatih Çakar YTU , İsmail Erol YTU , Özlem Cankurtaran YTU , Belkıs Bilgin Eran YTU

Molecular Crystals and Liquid Crystals

Abstract

A new chiral calamitic liquid crystal 4′-((S)-3,7-dimethyloctyloxy)phenyl 4-(10-undecen-1-yloxy)benzoate (DOPUB) has been synthesized and characterized by spectroscopic methods (1H-NMR and 13C-NMR). The focus is on the preparation of the nanocomposites of new chiral calamitic liquid crystal DOPUB/Organo-montmorillonite clay (OMMT) by solution intercalation method addition with OMMT contents 2.5, 5, and 7.5 wt% and determination of the morphology, thermal behavior, and crystalline properties of liquid crystal DOPUB/OMMT. Montmorillonite (MMT) modified by cationic surfactant cetyltrimethylammonium bromide (CTAB) for increasing the interaction of clay with DOPUB liquid crystal. The characterization of clay minerals and nanocomposites was investigated by X-ray diffraction. The mesomorphic behavior of liquid crystal (DOPUB) and the nanocomposites was investigated by differential scanning calorimetry (DSC) and optical polarizing microscopy (PM).

Keywords

Montmorillonite Liquid crystal Differential scanning calorimetry Nanocomposite Bromide Materials science Intercalation (chemistry) Chemical engineering Cationic polymerization Crystallography Organic chemistry Polymer chemistry Chemistry Nanotechnology Composite material

Subject Areas

Liquid Crystal Research Advancements ·Electronic, Optical and Magnetic Materials ·Physical Sciences
Polymer Nanocomposites and Properties ·Polymers and Plastics ·Physical Sciences
Surfactants and Colloidal Systems ·Organic Chemistry ·Physical Sciences

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