Abstract
Abstract Photoinitiated free radical polymerization of methylmethacrylate (MMA), (Nisopropylcarbamate) ethylpropenoate (CL-960) and tripropyleneglycol diacrylate (TPGDA) by using polysilanes in the presence of N-ethoxy-2 methyl pyridinium hexafluorophosphate (EMP+ PF6) and diphenyliodonium hexaflurophosphate (Ph2l+ PF6) was studied. In the presence of the cationic salts the rate of photopolymerization was significantly increased The effect was attributed to the oxidation of silyl radicals formed from the photoscission of polysilane by pyridinium or diphenliodonium salts. The resulting radicals species are more capable of initiating the radical polymerization.
Keywords
Cationic polymerization
Photopolymer
Pyridinium
Polysilane
Radical
Polymerization
Hexafluorophosphate
Chemistry
Polymer chemistry
Photochemistry
Radical polymerization
Alkoxy group
Silylation
Organic chemistry
Polymer
Catalysis
Ionic liquid
Alkyl
Subject Areas
Photopolymerization techniques and applications
·Organic Chemistry ·Physical Sciences
Synthesis and characterization of novel inorganic/organometallic compounds
·Inorganic Chemistry ·Physical Sciences
Silicone and Siloxane Chemistry
·Materials Chemistry ·Physical Sciences
Citations by Year
2017: 1
2021: 1
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