Journal Article

·2019

The synthesis and dielectric characterization of a low temperature smectic a liquid crystal

Pınar Çağlar YTU , Hale Ocak YTU , Nimet Yılmaz Canlı YTU , Alptekin Yıldız YTU , Mustafa Okutan YTU , Belkız Bilgin Eran YTU

Materials Research Express

Abstract

In the present paper, we have been synthesized a new salicylaldimine-based rod-like liquid crystal 4-((S)-3,7-Dimethyloctyloxy)-2-[[[4-(S)-2-methylbutoxyphenyl]imino]methyl]phenol (DMIP) exhibiting an enantiotropic Smectic A mesophase in the narrow temperature range. We have also evaluated the dielectric parameters of this liquid crystal DMIP as a function of temperature from 25 °C–50 °C and frequency range from 1 Hz to 1 MHz. It is observed that dielectric constant (e') and dielectric loss factor (e'') depends on frequency and temperature. Relative dielectric parameters, such as the dielectric strength, relaxation times and absorption coefficient change at phase transition temperature of the DMIP have been analyzed from the dielectric data of the Cole-Cole equation. Molecular reorientation mechanism has been investigated in the Smectic A mesophase temperature range by Debye type relaxation behaviour.

Keywords

Mesophase Dielectric Liquid crystal Relaxation (psychology) Atmospheric temperature range Materials science Crystal (programming language) Phase (matter) Absorption (acoustics) Phase transition Chemistry Thermodynamics Organic chemistry Composite material Optoelectronics

Subject Areas

Liquid Crystal Research Advancements ·Electronic, Optical and Magnetic Materials ·Physical Sciences
Nonlinear Dynamics and Pattern Formation ·Computer Networks and Communications ·Physical Sciences
Molecular spectroscopy and chirality ·Spectroscopy ·Physical Sciences

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