Abstract
Abstract Global population growth has led to an increase in the consumption of silver, which has a wide range of applications. This situation has increased demand for determining trace levels of silver to protect public health and the environment. In this study, an efficient magnetic-dispersive solid phase extraction (MDSPE) method was developed utilizing TiO 2 @Fe 3 O 4 nanocomposites (NCs) as adsorbent for the separation and preconcentration of silver ions. TiO 2 nanoparticles (NPs) were synthesized by a microwave-assisted hydrothermal method under different precursor solution and temperature program conditions. The procedure yielding TiO 2 NPs with the homogeneous size distribution was established, and the NPs obtained with this procedure were used to modify the Fe 3 O 4 surface. TiO 2 @Fe 3 O 4 NCs and TiO 2 NPs synthesized via alternative innovative methods to traditional techniques were examined by various characterization methods. Flame atomic absorption spectrometry (FAAS) was used for detection and quantification of analyte. All parameters expected to affect the adsorption and desorption of silver ions on the TiO 2 @Fe 3 O 4 NCs were optimized. In the developed procedure, the optimum parameters were 20 mg TiO 2 @Fe 3 O 4 NC, 1.5 mL potassium hydrogen phthalate buffer solution (pH 6.0), orbital agitation for 30 min, and 0.10 mL HNO 3 (2.0 M). The proposed novel TiO 2 @Fe 3 O 4 -MDSPE-FAAS method exhibits detection and quantification limits of 0.005 and 0.017 mg kg −1 in a wide linear working range for silver ions. The method’s relevance and accuracy were evaluated by recovery experiments conducted on both actual and synthetic residential wastewater samples, yielding satisfactory percent recovery results using a matrix-matching calibration strategy. Graphical abstract