Abstract
An aromatic bishalide, 5-tert-butyl-1,3-bis(4-fluorobenzoyl)benzene (2) was synthesized in high yield and purity by the reaction of 5-tert-butylisophthaloyl chloride (1) and fluorobenzene and polymerized by nucleophilic substitution reaction with commercially available aromatic bisphenols to prepare a series of high molecular weight poly(arylene ether ketone)s containing pendant tertiary butyl groups. The effect of molecular structure on the physical, thermal, mechanical and adhesion properties of the polymers was investigated.
Keywords
Arylene
Ether
Benzene
Nucleophilic aromatic substitution
Materials science
Ketone
Nucleophilic substitution
Polymer chemistry
Terephthaloyl chloride
Polymerization
Yield (engineering)
Polymer
Organic chemistry
Chemistry
Condensation polymer
Aryl
Composite material
Subject Areas
Synthesis and properties of polymers
·Polymers and Plastics ·Physical Sciences
Silicone and Siloxane Chemistry
·Materials Chemistry ·Physical Sciences
Epoxy Resin Curing Processes
·Mechanical Engineering ·Physical Sciences
Citations by Year
2020: 1
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